Apologies since this is not really a Rock 'n Roll song but another Wilson Pickett song that is notable since Duane Allman was on lead guitar as a sideman at Muscle Shoals. He doesn't really let loose until the final minute of the song.
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Definition of ROCK AND ROLL
popular music usually played on electronically amplified instruments and characterized by a persistent heavily accented beat, repetition of simple phrases, and often country, folk, and blues elements : rock —often used before another noun… See the full definition