Not worth it. And, the link from smiley1437 tells exactly why it doesn't work. Cathodic protection works only if the electrical circuit is complete. This is very difficult if not impossible, to do with a car. Having said that, there might be some old timers on this board who might remember positive ground systems in cars. These cars appeared to rust very fast, because the car body and chassis were positively polarised. For a car body to be cathodically protected, you would need a multitude of devices, or sacraficial anodes, to be installed at precise places. Zinc galvanising accomplishes the cathodic protection because the zinc acts as a sacrificial anode uniformly over the entire car body sheet metal.