NASA has confirmed that man has changed the gas/particulate contribution to warming and cooling. There is another issue. Methane bound in the bottom of the sea, if released, would quickly turn earth into a very hot planet. There are theories that global warming inhibits the release and others that it will lead to it. Much more needs to be understood - and quickly as warming will be ongoing for the next century no matter what we do now. The following is not copywrited and is exerpted from The Economist.
Methane and climate change
Swamp thing or monster of the deep?
Apr 17th 2003 | NICE
A discussion about the end of the last ice age has repercussions for today's climate
RESEARCHERS have known for a long time that a mixture of water and a gas such as methane can, in the right circumstances, form an ice-like substance called a clathrate, or gas hydrate, at temperatures above normal freezing point. Ice has an open molecular structure (this is why water, unlike most liquids, expands when it freezes, and thus bursts pipes in the winter). Add a bit of pressure and that openness will accommodate gas molecules. These, in turn, lend support to ice crystals that would otherwise melt. Pressure is one of the things that the bottom of the sea is famous for. So, if you add a source of methane, conditions there are often ideal for the formation of clathrates.
But clathrates are hard to study. Once dredged up, they quickly melt, and the gas is released.
The discussion on clathrates and the end of the ice age was one of the topics at a joint meeting of the American Geological Union, the European Geological Society and the European Union of Geosciences which has just been held in Nice. It revolves around the cause of a large release of methane into the atmosphere at the end of the last ice age. This is known to have happened because it has left traces in air-bubbles trapped in ancient ice. Methane is a greenhouse gas—and a far more powerful one than carbon dioxide. It is reasonable to think that a big methane release and the end of an ice age might be more than coincidental. Where this methane came from matters because, at the moment, something between 2 trillion and 8 trillion tonnes of methane is thought to be locked up in under-sea clathrates. If it suddenly “burped� up, the Earth could be in for a torrid time.
There are two schools of thought about the origins of the methane released at the end of the ice age. One, championed by James Kennett, a paleo-oceanographer from the University of California, Santa Barbara, is that it was indeed released from clathrates. The argument goes like this. Suppose the oceans warm up a bit, as they regularly do as part of natural climate cycles. A significant amount of methane hydrate could suddenly find itself outside its stability zone and thus separate into water molecules and methane gas. The gas would soon find its way into the atmosphere, where it would add to the greenhouse effect and cause the temperature to rise. That, in turn, would cause further methane release. In other words, there would be positive feedback that could end up dumping a lot of methane into the atmosphere. On this view of things, the methane at the bottom of the ocean is something to worry about.
It is a neat idea. However, there is an equally persuasive argument that runs counter to it. This is that a warming atmosphere will melt ice at the poles. That will raise the sea level, increasing the pressure at the bottom and thus stabilising clathrates there—in other words, there will be negative feedback. But if that is true, then the methane spike at the end of the ice age must have been caused by something else.
(THe rest of the artical is good reading but a) to long for this thread and b) goes into molecular analysis of various carbon isotopes which is not conclusive either way. Some highlights)
Dr Maslin's computer models of the expansion of life on earth as the glaciers receded suggest that about a trillion tonnes of extra carbon was sucked out of the atmosphere to help to manufacture all those extra leaves, stalks and trunks.
A significant release of hydrate methane, low in 13C, would counteract the increase in 13C concentration caused by the greening of the world. In Dr Maslin's carbon budget, such a release “hid� a lot of the world's new forests from view.
One up, it would appear, to Dr Kennett. However, when the calculation is done in detail, the amount of hydrate-derived methane needed to balance the isotopic equations is only 100 billion tonnes. That is far less than the actual increase of methane in the atmosphere in the period in question.
Perhaps, therefore, the negative feedback model is dominant. But the debate is not over yet. Dr Kennett, perfectly reasonably, asks where the geological evidence is for all those extra swamps.