In my classic car (circa 1969 through 74), I only use 94 from PC. That's because I've shaved the head to achieve a 9.75:1 compression ratio AND, I've advanced the timing in order to improve acceleration.
That said, ethanol in gasoline is a very very very bad thing. It will gum up a car's engine in no time flat. My sister has a newer Audi Q5 with the 3.2 litre motor and the engine was so fucked up by ethanol in the fuel that the vehicle had to have the engine pulled and torn apart in order to clean out the gum from ethanol. Audi is well aware of the problem. Fortunately for her, the car was still under warrantee and she was told that Audi is extending the warrantee on this issue.
In my case, I've seen the damage ethanol can cause to the old carbeurator engines. Fuel bowls look like they have been running on swamp water, valves gummed up, fuel pumps fucked up.
This stuff is a disaster and should be avoided at all costs.
I emailed PC, Esso, and Husky asking them all specific questions about ethanol. Only Husky would say that their 91 Octane fuels do not contain ethanol EVER. PC and Esso both avoided the question and gave some BS nonanswer response.
I had been told that Shell fuels don't contain ethanol by a friend and now I'm reading it here too.
I think a switch to Shell is in order.